Zirconium disulfide

Zirconium(IV) sulfide[1]
Names
IUPAC name
Zirconium(IV) sulfide
Identifiers
12039-15-5
ECHA InfoCard 100.031.701
Properties
ZrS2
Molar mass 155.356 g/mol
Appearance red-brown crystals
Density 3.82 g/cm3
Melting point 1,480 °C (2,700 °F; 1,750 K)
insoluble
Structure
Rhombohedral, hP3, SpaceGroup = P-3m1, No. 164
octahedral
Hazards
Safety data sheet MSDS
not listed
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Infobox references

Zirconium(IV) sulfide is the inorganic compound with the formula ZrS2. It is a violet-brown solid. It adopts a layered structure similar to that of cadmium iodide.

Like the closely related titanium disulfide, ZrS2 is prepared by heating sulfur and zirconium metal. It can be purified by vapor transport using iodine.[2]

References

  1. Lide, David R. (1998), Handbook of Chemistry and Physics (87 ed.), Boca Raton, FL: CRC Press, pp. 4–96, ISBN 0-8493-0594-2
  2. Lawrence E. Conroy "Group IV Sulfides" Inorganic Synthesis 1970, XII, 158. doi:10.1002/9780470132432.ch28
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