Vanadiocarpholite

Vanadiocarpholite
General
Category Silicate mineral
Formula
(repeating unit)
Mn+2V+3AlSi2O6(OH)4
Strunz classification 9.DB.05
Crystal system Orthorhombic
Crystal class Dipyramidal (mmm)
H-M symbol: (2/m 2/m 2/m)
Space group Ccca
Unit cell a = 13.83 Å, b = 20.681 Å
c = 5.188 Å; Z = 8
Identification
Color Pale-straw yellow, honey-yellow to brown
Crystal habit Prismatic to acicular crystal clusters, vein fillings
Cleavage Perfect on {010}
Tenacity Flexible
Luster Vitreous, silky
Diaphaneity Transparent
Optical properties Biaxial (+)
Refractive index nα=1.684, nβ=1.691, nγ=1.7
Birefringence 0.0160
References [1][2]

Vanadiocarpholite (Mn+2V+3AlSi2O6(OH)4) is straw yellow to brown silicate mineral. It crystallizes in the orthorhombic crystal system. It is the vanadium rich variety of carpholite (Mn+2Al2Si2O6(OH)4).

Discovery and occurrence

It was first described in 2005 for an occurrence in the Molinello Mine, Graveglia Valley, Genova Province, Liguria, Italy.[2] It occurs in chert in a manganese ore deposit as vein fillings in silicified wood.[1]

Chemical composition

It consists of:[1]

Manganese 15.56% Mn 20.09% MnO
Aluminium 7.64% Al 14.44% Al2O3
Vanadium 14.43% V 21.23% V2O3
Silicon 15.91% Si 34.04% SiO2
Hydrogen 1.14% H 10.21% H2O
Oxygen 45.32% O

References

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