Platinum group

Platinum group metals (PGMs) in the periodic table
H  He
LiBe  B C N O F Ne
NaMg  AlSiP S ClAr
K CaScTiVCrMnFeCoNiCuZnGaGeAsSeBrKr
RbSrY ZrNbMoTcRuRhPdAgCdInSnSbTeI Xe
CsBa * HfTaWReOsIrPtAuHgTlPbBiPoAtRn
FrRa ** RfDbSgBhHsMtDsRgCnNhFlMcLvTsOg
 * LaCePrNdPmSmEuGdTbDyHoErTmYb
**AcThPaU NpPuAmCmBkCfEsFmMdNo
   Platinum group metals
   Other noble metals

The platinum-group metals (abbreviated as the PGMs; alternatively, the platinoids, platinides, platidises, platinum group, platinum metals, platinum family or platinum-group elements (PGEs)) are six noble, precious metallic elements clustered together in the periodic table. These elements are all transition metals in the d-block (groups 8, 9, and 10, periods 5 and 6).[1][1]

The six platinum-group metals are ruthenium, rhodium, palladium, osmium, iridium, and platinum. They have similar physical and chemical properties, and tend to occur together in the same mineral deposits.[2] However they can be further subdivided into the iridium-group platinum-group elements (IPGEs: Os, Ir, Ru) and the palladium-group platinum-group elements (PPGEs: Rh, Pt, Pd) based on their behaviour in geological systems.[3]

The three elements above the platinum group in the traditional periodic table (iron, nickel and cobalt) are all ferromagnetic, these being the only known transition metals with this property.

History

Naturally occurring platinum and platinum-rich alloys have been known by pre-Columbian Americans for many years.[4] Though the metal was used by pre-Columbian peoples, the first European reference to platinum appears in 1557 in the writings of the Italian humanist Julius Caesar Scaliger (1484–1558) as a description of a mysterious metal found in Central American mines between Darién (Panama) and Mexico ("up until now impossible to melt by any of the Spanish arts").[4]

The Spaniards named the metal platina ("little silver") when they first encountered it in Colombia. They regarded platinum as an unwanted impurity in the silver they were mining.[4][5]

Properties and uses

Replica of the NIST national prototype kilogram standard, made in 90%platinum - 10%iridium alloy.

As of 1996, the largest applications of platinum metals were, in millions of troy ounces/year: Pd for autocatalysts (4470), Pt for jewelry (2370), Pd for electronics (2070), Pt for autocatalysts (1830), Pd for dental (1230), Rh for autocatalysts (490), and Pd for chemical reagents (230).[1]

The platinum metals have many useful catalytic properties. They are highly resistant to wear and tarnish, making platinum, in particular, well suited for fine jewelry. Other distinctive properties include resistance to chemical attack, excellent high-temperature characteristics, and stable electrical properties. All these properties have been exploited for industrial applications.[6]

Occurrence

Generally, ultramafic and mafic igneous rocks have relatively high, and granites low, PGE trace content. Geochemically anomalous traces occur predominantly in chromian spinels and sulfides. Mafic and ultramafic igneous rocks host practically all primary PGM ore of the world. Mafic layered intrusions, including the Bushveld Complex, outweigh by far all other geological settings of platinum deposits.[7] Other economically significant PGE deposits include mafic intrusions related to flood basalts, and ultramafic complexes of the Alaska, Urals type.[8]

PGM minerals

Typical ores for PGMs contain ca. 10 g PGM/ton ore, thus the identity of the particular mineral is unknown.[9]

Platinum

Sperrylite (platinum arsenide, PtAs2) ore is a major source of this metal. A naturally occurring platinum-iridium alloy, platiniridium, is found in the mineral cooperite (platinum sulfide, PtS). Platinum in a native state, often accompanied by small amounts of other platinum metals, is found in alluvial and placer deposits in Colombia, Ontario, the Ural Mountains, and in certain western American states. Platinum is also produced commercially as a by-product of nickel ore processing. The huge quantities of nickel ore processed makes up for the fact that platinum makes up only two parts per million of the ore. South Africa, with vast platinum ore deposits in the Merensky Reef of the Bushveld complex, is the world's largest producer of platinum, followed by Russia.[10][11] Platinum and palladium are also mined commercially from the Stillwater igneous complex in Montana, USA. Leaders of primary platinum production are South Africa and Russia, followed by Canada, Zimbabwe and USA.

Osmium

Osmiridium is a naturally occurring alloy of iridium and osmium found in platinum-bearing river sands in the Ural Mountains and in North and South America. Trace amounts of osmium also exist in nickel-bearing ores found in the Sudbury, Ontario region along with other platinum group metals. Even though the quantity of platinum metals found in these ores is small, the large volume of nickel ores processed makes commercial recovery possible.[11][12]

Iridium

Metallic iridium is found with platinum and other platinum group metals in alluvial deposits. Naturally occurring iridium alloys include osmiridium and iridosmine, both of which are mixtures of iridium and osmium. It is recovered commercially as a by-product from nickel mining and processing.[11]

Ruthenium

Ruthenium is generally found in ores with the other platinum group metals in the Ural Mountains and in North and South America. Small but commercially important quantities are also found in pentlandite extracted from Sudbury, Ontario and in pyroxenite deposits in South Africa.[11]

Rhodium

The industrial extraction of rhodium is complex, because it occurs in ores mixed with other metals such as palladium, silver, platinum, and gold. It is found in platinum ores and obtained free as a white inert metal which is very difficult to fuse. Principal sources of this element are located in river sands of the Ural Mountains, in North and South America and also in the copper-nickel sulfide mining area of the Sudbury Basin region. Although the quantity at Sudbury is very small, the large amount of nickel ore processed makes rhodium recovery cost effective. However, the annual world production in 2003 of this element is only 7 or 8 tons and there are very few rhodium minerals.[13]

Palladium

Palladium is preferentially hosted in sulphide minerals, primarily in pyrrhotite.[7] Palladium is found as a free metal and alloyed with platinum and gold with platinum group metals in placer deposits of the Ural Mountains of Eurasia, Australia, Ethiopia, South and North America. However it is commercially produced from nickel-copper deposits found in South Africa and Ontario, Canada. The huge volume of nickel-copper ore processed makes this extraction profitable in spite of its low concentration in these ores.[13]

Production

Process flow diagram for the separation of the platinum group metals.

The production of individual platinum group metals normally starts from residues of the production of other metals with a mixture of several of those metals. Purification typically starts with the anode residues of gold, copper, or nickel production. Thus, the extraction process is very energy intensive with environmental consequences. Classical purification methods exploit differences in chemical reactivity and solubility of several compounds of the metals under extraction.[6] These approaches have yielded to new technologies that utilize solvent extraction.

Separation begins with dissolution of the sample. If aqua regia is used, the chloride complexes are produced. Depending on the details of the process, which are often trade secrets, the individual PGMs are obtained as the following compounds: (NH4)2PtCl6, PdCl2(NH3)2, the volatile OsO4 and RuO4, the poorly soluble (NH4)2IrCl6, and [RhCl(NH3)5]Cl2.[9]

Production in nuclear reactors

Significant quantities of the three light platinum group metals—ruthenium, rhodium and palladium—are formed as fission products in nuclear reactors.[14] With escalating prices and increasing global demand, reactor-produced noble metals are emerging as an alternative source. Various reports are available on the possibility of recovering fission noble metals from spent nuclear fuel.[15][16][17]

See also

Notes

  1. 1 2 3 Renner, H.; Schlamp, G.; Kleinwächter, I.; Drost, E.; Lüschow, H. M.; Tews, P.; Panster, P.; Diehl, M.; et al. (2002). "Platinum group metals and compounds". Ullmann's Encyclopedia of Industrial Chemistry. Wiley. doi:10.1002/14356007.a21_075.
  2. ↑ Harris, D. C.; Cabri L. J. (1991). "Nomenclature of platinum-group-element alloys; review and revision". The Canadian Mineralogist. 29 (2): 231–237.
  3. ↑ Rollinson, Hugh (1993). Using Geochemical Data: Evaluation, Presentation, Interpretation. Longman Scientific and Technical. ISBN 0-582-06701-4.
  4. 1 2 3 Weeks, M. E. (1968). Discovery of the Elements (7 ed.). Journal of Chemical Education. pp. 385–407. ISBN 0-8486-8579-2. OCLC 23991202.
  5. ↑ Woods, Ian (2004). The Elements: Platinum. Benchmark Books. ISBN 978-0-7614-1550-3.
  6. 1 2 Hunt, L. B.; Lever, F. M. (1969). "Platinum Metals: A Survey of Productive Resources to industrial Uses" (PDF). Platinum Metals Review. 13 (4): 126–138. Retrieved 2009-10-02.
  7. 1 2 Walter L. Pohl, Economic Geology Principles and Practice 2011
  8. ↑ Walter L. Pohl, Economic Geology Principles and Practice 2011, P 230
  9. 1 2 Bernardis, F. L.; Grant, R. A.; Sherrington, D. C. "A review of methods of separation of the platinum-group metals through their chloro-complexes" Reactive and Functional Polymers 2005, Vol. 65,, p. 205-217. doi:10.1016/j.reactfunctpolym.2005.05.011
  10. ↑ Xiao, Z.; Laplante, A. R. (2004). "Characterizing and recovering the platinum group minerals—a review". Minerals Engineering. 17 (9–10): 961–979. doi:10.1016/j.mineng.2004.04.001.
  11. 1 2 3 4 "Platinum–Group Metals" (PDF). U.S. Geological Survey, Mineral Commodity Summaries. January 2007. Retrieved 2008-09-09.
  12. ↑ Emsley, J. (2003). "Iridium". Nature's Building Blocks: An A-Z Guide to the Elements. Oxford, England, UK: Oxford University Press. pp. 201–204. ISBN 0-19-850340-7.
  13. 1 2 Chevalier, Patrick. "Mineral Yearbook: Platinum Group Metals" (PDF). Natural Resources Canada. Retrieved 2008-10-17.
  14. ↑ R. J. Newman, F. J. Smith (1970). "Platinum Metals from Nuclear Fission – an evaluation of their possible use by the industry" (PDF). Platinum Metals Review. 14 (3): 88.
  15. ↑ Zdenek Kolarik, Edouard V. Renard (2003). "Recovery of Value Fission Platinoids from Spent Nuclear Fuel; PART I: general considerations and basic chemistry" (PDF). Platinum Metals Review. 47 (2): 74.
  16. ↑ Kolarik, Zdenek; Renard, Edouard V. (2005). "Potential Applications of Fission Platinoids in Industry" (PDF). Platinum Metals Review. 49 (2): 79. doi:10.1595/147106705X35263.
  17. ↑ Zdenek Kolarik, Edouard V. Renard (2003). "Recovery of Value Fission Platinoids from Spent Nuclear Fuel; PART II: Separation process" (PDF). Platinum Metals Review. 47 (3): 123.

External links

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